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Tetra­aqua­tetrakis­(di­methyl­acet­amide-κO)­neodymium(III) hexa­cyano­ferrate(III) trihydrate

✍ Scribed by Overgaard, Jacob ;Svendsen, Helle ;Chevalier, Marie A. ;Iversen, Bo B.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
205 KB
Volume
61
Category
Article
ISSN
1600-5368

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In the title compound, [Ce(C 6 H 4 NO 2 ) 3 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á-3H 2 O, the Ce III atom shows a capped trigonal prismatic N 4 O 5 coordination. The CeÐO and CeÐN bond distances are 2.390 (2)±2.517 (2) and 2.730 (3)±2.752 (3) A Ê , respectively.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.032 wR factor = 0.065 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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