Dipotassium ethane-1,1-diylbis(diazeniumdiolate) monohydrate
✍ Scribed by Arulsamy, Navamoney ;Bohle, D. Scott
- Book ID
- 104483817
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 186 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The ethane-1,1-bis(diazeniumdiolate) anion in the title compound, 2K + ÁC 2 H 4 N 4 O 4 2À ÁH 2 O, acts as a complex bridging ligand. Both the N and the O atoms of the diazeniumdiolate substituents are coordinated to the K + cations, revealing the delocalization of a negative charge over the four-atom groups.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.010 A Ê R factor = 0.055 wR factor = 0.145 Data-to-parameter ratio = 13.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The Co II atom in the title compound, [Co(C 16 H 14 N 2 O 2 )], has a square-planar coordination. metal-organic papers Acta Cryst. (2006). E62, m3504-m3505 Yuan et al. [Co(C 16 H 14 N 2 O 2 )] m3505
The title compound, [Ni(C 10 H 22 N 2 S 2 )], contains a squareplanar Ni center coordinated by the tetradentate ligand 3,3 0 -[ethane-1,2-diylbis(methylimino)]dipropane-1-thiolate. Upon chelation, the N 2 S 2 ligand generates one five-membered chelate ring containing the N donors and two six-membere