Dinitrogen-Bond Cleavage in a Niobium Complex Supported by a Tridentate Aryloxide Ligand
β Scribed by Hiroyuki Kawaguchi; Tsukasa Matsuo
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 96 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Pyrrole-based polyanions are versatile ligands for f block metals which have been proved capable of assembling large cluster structures and of substantially increasing the reactivity of their low-valent derivatives. This is especially evident in the chemistry of divalent samarium, where the utilizat
## Abstract Reaction of a Cu^I^ complex of a hybrid tridentate ligand, encompassing [2β(pyridinβ2βyl)ethyl]amine and dimethylβsubstituted ethylalkylamine with dioxygen, generates in acetone at β80Β° putative bis(__ΞΌ__βoxo)dicopper(III) intermediate. Structural characterization of a PPh~3~βadduct of
## Abstract **It's in the bond**: The cleavage of Cο£ΏH bonds by two related oxoiron(IV) complexes shows a range of kinetic isotope effect (KIE) values that exhibit an unusual dependence on the Cο£ΏH bond strength. Large nonclassical KIEs are observed for bond strengths below 93β kcalβmol^β1^, while sem