𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes

✍ Scribed by Eric J. Klinker; Sason Shaik; Hajime Hirao; Lawrence Que Jr.

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
315 KB
Volume
121
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A Two-State Reactivity Model Explains Un
A Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes
✍ Eric J. Klinker; Sason Shaik; Hajime Hirao; Lawrence Que Jr. 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB 👁 1 views

## Abstract **It's in the bond**: The cleavage of CH bonds by two related oxoiron(IV) complexes shows a range of kinetic isotope effect (KIE) values that exhibit an unusual dependence on the CH bond strength. Large nonclassical KIEs are observed for bond strengths below 93 kcal mol^−1^, while sem