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A Highly Reactive Uranium Complex Supported by the Calix[4]tetrapyrrole Tetraanion Affording Dinitrogen Cleavage, Solvent Deoxygenation, and Polysilanol Depolymerization

โœ Scribed by Ilia Korobkov; Sandro Gambarotta; Glenn P. A. Yap


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
114 KB
Volume
41
Category
Article
ISSN
0044-8249

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A Highly Reactive Uranium Complex Suppor
โœ Ilia Korobkov; Sandro Gambarotta; Glenn P. A. Yap ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 114 KB

Pyrrole-based polyanions are versatile ligands for f block metals which have been proved capable of assembling large cluster structures and of substantially increasing the reactivity of their low-valent derivatives. This is especially evident in the chemistry of divalent samarium, where the utilizat