Dimorphie von kristallinem Acetonitril-tris(η5- cyclopentadienyl) samarium(III)
✍ Scribed by Martin Adam; Holger Schultze; R.Dieter Fischer
- Book ID
- 107812256
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 206 KB
- Volume
- 429
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
By comparison of the energies of the observed bands in the low temperature absorption spectrum of tris(q5-cyc~opentadienyl)-praseodymium(III)-cycIohexylis~yanide with the calculated crystal field splitting pattern (which is based on a fit of 17 signals in the magnetic circular dichroism spectrum) th
On the basis of the magnetic circular dichroism spectra of the transitions 3H, + 'DZ and 3H, + 'P,, respectively, of Cp,Pr adducts the main contributions of I+ J, ) in the eigenvectors of both manifolds could be identified. Neglecting g, the remaining crystal field parameters B& B& S& Bz and Bz adop