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Zur Elektronenstruktur metallorganischer Komplexe der ⨍-Elemente—X. Zuordnung der Banden im Absorptionsspektrum von Tris(η5-cyclopentadienyl)-praseodym(III)-cyclohexylisonitril

✍ Scribed by H.-D. Amberger; W. Jahn

Book ID
103905713
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
607 KB
Volume
41
Category
Article
ISSN
1386-1425

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✦ Synopsis

By comparison of the energies of the observed bands in the low temperature absorption spectrum of tris(q5-cyc~opentadienyl)-praseodymium(III)-cycIohexylis~yanide with the calculated crystal field splitting pattern (which is based on a fit of 17 signals in the magnetic circular dichroism spectrum) the underlying electronic structure could be elucidated.

📜 SIMILAR VOLUMES

Zur Elektronenstruktur metallorganischer
Zur Elektronenstruktur metallorganischer Komplexe der f– Element—VIII. Welche Vorzeichen haben die Kristallfeld-Parameter von Tris(η5-cyclopentadienyl)-lanthanoid(III)-Addukten
✍ H.-D. Amberger; W. Jahn 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 766 KB

On the basis of the magnetic circular dichroism spectra of the transitions 3H, + 'DZ and 3H, + 'P,, respectively, of Cp,Pr adducts the main contributions of I+ J, ) in the eigenvectors of both manifolds could be identified. Neglecting g, the remaining crystal field parameters B& B& S& Bz and Bz adop