๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Dimethylthiocarbamate (DMTC): An Alcohol Protecting Group.

โœ Scribed by D. K. Barma; A. Bandyopadhyay; Jorge H. Capdevilla; J. R. Falck

Book ID
101954329
Publisher
John Wiley and Sons
Year
2004
Weight
215 KB
Volume
35
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

An alkyne protecting group
An alkyne protecting group
โœ K.M. Nicholas; R. Pettit ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 168 KB

Due to the greater reactivity of triple bonds to several of the more common addition reactions, (i.e. reduction, 1 hydroboration,2 and acid-catalyzed hydration3) it is generally very difficult to selectively induce double bonds to undergo addition in the presence of triple bonds. We report

The sisyl (tris(trimethylsilyl)silyl) gr
The sisyl (tris(trimethylsilyl)silyl) group: A fluoride resistant, photolabile alcohol protecting group
โœ Michael A. Brook; Christine Gottardo; Sonya Balduzzi; Mustafa Mohamed ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

The use of the tris(trimethylsilyl)silyl (sisyl) group as a photolabile protecting group for primary and secondary alcohols was demonstrated. Sisyl ethers of a number of alcohols (yields 70-97%) were stable to many synthetic protocols, but could be deprotected using photolysis to give the starting a

The diethylisopropylsilyl group: A new p
The diethylisopropylsilyl group: A new protecting group for alcohols
โœ Kazunobu Toshima; Satsuki Mukaiyama; Mitsuhiro Kinoshita; Kuniaki Tatsuta ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 167 KB

The diethylisopropylsilyl (DEIPS) group which is a new protective group for alcohols has been first characterized. DEIPS group can be distinguished from t-butyldimethylsilyl, triethylsilyl, tetrahydropyranyl groups and 2-deoxy glycoside with high selectivity in removing under mild acidic condition,