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Dimethylsilylene: its optical absorption spectrum and reaction kinetics

โœ Scribed by Nazran, A. S.; Hawari, J. A.; Griller, D.; Alnaimi, I. S.; Weber, W. P.


Book ID
127104235
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
301 KB
Volume
106
Category
Article
ISSN
0002-7863

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The transient absorption of dodeeamethylcyclohexasilane in methylcyclohexane at 470 nm obtained by laser photolysis is due to dimethylsilylene, which decays exponentially with a lifetime of ~200 ns at 293 K. The reaction rate of dimethyisilylene with methanol or triethylsilane is close to the diffus