CH,CHOH radicals have been studied using a pulse radiolysis/kinetic absorption technique. The UV spectrum of this species has been measured at wavelengths between 230 and 300 nm with a maximum absorption cross-section of 3.6 x lo-" cm2 molecule-' at 238 nm. Kinetic studies at 300 K yielded rate cons
Near-UV Absorption Spectrum of the Phenoxyl Radical and Kinetics of Its Reaction with CH 3†
✍ Scribed by Tonokura, Kenichi; Ogura, Teppei; Koshi, Mitsuo
- Book ID
- 125940781
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 80 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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The UV absorption spectrum and the kinetics of the self combination reaction of the CCl, radical were studied by flash photolysis in the temperature range 253-623 K. Experiments were performed at the atmospheric pressure, except for a few runs a t the highest temperatures, which were performed betwe