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Correction. Dimethylsilylene: Its Optical Absorption Spectrum and Reaction Kinetics

โœ Scribed by Nazran, A S.; Hawari, J A.; Griller, D.; Alnaimi, I S.; Weber, W P.

Book ID
127333938
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
120 KB
Volume
108
Category
Article
ISSN
0002-7863

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The transient absorption of dodeeamethylcyclohexasilane in methylcyclohexane at 470 nm obtained by laser photolysis is due to dimethylsilylene, which decays exponentially with a lifetime of ~200 ns at 293 K. The reaction rate of dimethyisilylene with methanol or triethylsilane is close to the diffus