Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ 3N , N ′, N ′′]copper(II)
✍ Scribed by Chen, Feng-Tao
- Book ID
- 120256714
- Publisher
- International Union of Crystallography
- Year
- 2010
- Tongue
- English
- Weight
- 584 KB
- Volume
- 66
- Category
- Article
- ISSN
- 1600-5368
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metal-organic compounds m1976 Martı ´nez-Vargas et al. [Cu(C 7 H 4 NO 4 )(C 21 H 15 N 3 )]BF 4
In the title complex, [Mn(C 22 H 17 N 3 ) 2 ](ClO 4 ) 2 , the MnN 6 coordination geometry is distorted octahedral, involving the six N atoms of two 4 0 -(4-methylphenyl)-2,2 0 :6 0 ,2 00 -terpyridine (ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 (
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.051 wR factor = 0.134 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.