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[4′-(4-Pyridyl)-2,2′:6′,2′′-ter­pyridine-κ3N,N′,N′′]­di­thio­cyanato­zinc(II)

✍ Scribed by Hou, Lei ;Li, Dan ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
185 KB
Volume
60
Category
Article
ISSN
1600-5368

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[4′-(2-Pyridyl)-2,2′:6′,2′′-ter­pyridine
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In the title complex, [Mn(C 22 H 17 N 3 ) 2 ](ClO 4 ) 2 , the MnN 6 coordination geometry is distorted octahedral, involving the six N atoms of two 4 0 -(4-methylphenyl)-2,2 0 :6 0 ,2 00 -terpyridine (ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 (

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The Zn^II^ centre in the title compound, [ZnBr~2~(C~12~H~9~IN~2~)], is covalently bonded to two Br atoms and two N atoms of the diimine ligand in a distorted tetrahedral geometry.