Diffusive transient recombination kinetics of interacting molecules
β Scribed by A.I. Shushin
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 443 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A simple analytical approach to diffusive geminate rgombination kinetics of interacting molecules is considered. The expressions obtained describe accurately the transient time dependence and show that the kinetics is exponenllal al short times and follows a power law at long times. This approach is applied to some time-resolved experimenls on ion-radical pair recombination.
π SIMILAR VOLUMES
The Smoluchowski equation for a pair of molecules with anisotropic reactivity and interaction potential is solved in the limit of a small reactive region (small reactive patches). In the steady-state case steric factors are calculated using this solution. The kinetics of geminate pair recombination
## Abstract Starting from the general telegrapher's equation, we investigate two nodal network constructions for modelling diffusion with recombination by means of the transmissionβline matrix (TLM) method. The diffusion effect is modelled by the series and shunt capacitance in one approach, and by