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Recombination kinetics of molecules with anisotropic reactivity and interaction potential. Exact solution for a small reactive region

✍ Scribed by A.I. Shushin


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
528 KB
Volume
130
Category
Article
ISSN
0009-2614

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✦ Synopsis


The Smoluchowski equation for a pair of molecules with anisotropic reactivity and interaction potential is solved in the limit of a small reactive region (small reactive patches). In the steady-state case steric factors are calculated using this solution. The kinetics of geminate pair recombination is also obtained and analyzed in detail. = 0 and GJ Q ' i> -k(dh&Q = O,