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Differences in the CO photolability of cis- and trans-[RuCl2(azpy)(CO)2] complexes: Effect of metal-to-ligand back-bonding

โœ Scribed by Carrington, Samantha J.; Chakraborty, Indranil; Alvarado, Joshua R.; Mascharak, Pradip K.


Book ID
120900915
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
637 KB
Volume
407
Category
Article
ISSN
0020-1693

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transโ€“cis Photoisomerization of the Styr
โœ Julien Bossert; Chantal Daniel ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 274 KB ๐Ÿ‘ 1 views

## Abstract The __transโ€cis__ isomerization of the styrylpyridine carbonโ€“carbon double bond induced by visible light irradiation in __fac__โ€[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2โ€ฒโ€bipyridine; stpy = __t__โ€4โ€styrylpyridine) has been investigated by means of quantumโ€chemical methods. The structures