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Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 7. Photochemistry of (CO)4CoM(CO)3(bpy) (M = Mn, Re; bpy = 2,2'-bipyridine): photocatalytic disproportionation of the manganese complex in the presence of PR3

✍ Scribed by Van Dijk, Hans K.; Van der Haar, Jos; Stufkens, Derk J.; Oskam, Ad


Book ID
127138516
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
902 KB
Volume
28
Category
Article
ISSN
0020-1669

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trans–cis Photoisomerization of the Styr
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## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures