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Diene-Ligated Iridium Catalyst for Allylation Reactions of Ketones and Imines

✍ Scribed by Barker, Timothy J.; Jarvo, Elizabeth R.


Book ID
124073258
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
106 KB
Volume
11
Category
Article
ISSN
1523-7060

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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the