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ChemInform Abstract: Diene-Ligated Iridium Catalyst for Allylation Reactions of Ketones and Imines.

✍ Scribed by Timothy J. Barker; Elizabeth R. Jarvo


Publisher
John Wiley and Sons
Year
2009
Weight
25 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the