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Diels—Alder Reactions of N-Acyl-2-alkyl(aryl)-5-vinyl-2,3-dihydro-4-pyridones.

✍ Scribed by Daniel L. Comins; Jeffrey T. Kuethe; Teresa M. Miller; Florence C. Fevrier; Clinton A. Brooks


Publisher
John Wiley and Sons
Year
2005
Weight
41 KB
Volume
36
Category
Article
ISSN
0931-7597

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ChemInform Abstract: C-3 Acetoxylation o
✍ D. L. COMINS; D. A. STOLZE; P. THAKKER; C. L. MCARDLE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

C-3 Acetoxylation of N-Acyl-2,3-dihydro-4-pyridones. -Stereoselective C-3 acetoxylation of various N-acyldihydropyridones (I) is achieved under mild conditions using lead tetraacetate. The analogous reaction of the indolizidinone (IV) to the cis product proceeds with considerably lower yield.