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Diels—Alder Reactions of 5-Vinyl-1-acyl-2-aryl-2,3-dihydro-4-pyridones: Regio- and Stereoselective Synthesis of Octahydroquinolines.

✍ Scribed by Jeffrey T. Kuethe; Clinton A. Brooks; Daniel L. Comins

Publisher: John Wiley and Sons
Year: 2003
Weight: 30 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200324112

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Diels-Alder Reactions of 5,6-Dihydro-2(1H)-pyridones. Preparation of Partially Reduced cis-Isoquinolones and cis-3,4-Disubstituted Piperidines. -Dihydropyridones (I) and (IV) undergo thermal or Lewis acid induced Diels-Alder reaction with various butadienes to give cisisoquinolone derivatives. cis-