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Diels-Alder reactions of Fischer carbene complexes

✍ Scribed by Wulff, William D.; Yang, Dominic C.


Book ID
126301614
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
265 KB
Volume
105
Category
Article
ISSN
0002-7863

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Asymmetric Diels–Alder Reactions with Ch
✍ Annette Rahm; Arnold L. Rheingold; William D. Wulff 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 267 KB

AbstractÐA new synthetic method is developed for the asymmetric Diels±Alder reactions of acetylenic dienophiles. Acetylenic Fischer carbene complexes with chiral pyrrolidines as the heteroatom stabilizing substituent were anticipated to block three of the four possible approaches of a diene and lead