𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Manganese and tungsten carbene complex mediated intramolecular Diels-Alder reactions

✍ Scribed by K.H. Dötz; D. Böttcher; M. Jendro


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
864 KB
Volume
222
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Facile synthesis of enantiopure tricycli
✍ Heh-Lung Huang; Heh-Chang Huang; Rai-Shung Liu 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 282 KB

Chiral furanyl diene 1 is easily prepared from cycloalkenation of chiral tungsten alkynol with acetaldehyde, followed by demetalation with Me 3 NO. This diene bears a chiral 1,3-dioxolane group to control diastereoselective Diels-Alder reactions with electron-deficient olefins. The chiral 1,3-dioxol