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Diels-Alder in Aqueous Molecular Hosts: Unusual Regioselectivity and Efficient Catalysis

✍ Scribed by Yoshizawa, Michito (author);Tamura, Masazumi (author);Fujita, Makoto (author)

Book ID
115468882
Publisher
American Association for the Advancement of Science
Year
2006
Tongue
English
Weight
473 KB
Volume
312
Category
Article
ISSN
0036-8075

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πŸ“œ SIMILAR VOLUMES

β€œMicellar” catalysis in the aqueous inte
β€œMicellar” catalysis in the aqueous intermolecular diels-alder reaction: rate acceleration and enhanced selectivity
✍ Paul A. Grieco; Philip Garner; Zhen-min He πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 192 KB

The intermolecular Diels-Alder reactions employing dienophiles k and 2 with diene < have been examined in water. The significantly enhanced rates, as well as the improved selectivity observed in water stand in sharp contrast to the results observed in hydrocarbon solvents: