ChemInform Abstract: Efficient Lanthanoid Catalysis in the Diels-Alder Cycloaddition of Electron-Deficient 2-Pyrones (I).
✍ Scribed by I. E. MARKO; G. R. EVANS
- Book ID
- 112020760
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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Remarkable Effect of Basic Ligands in the Lanthanoid-Catalyzed Enantioselective Cycloadditions of 3-Carbomethoxy-2-pyrone (3-CMP). -The enantioselectivity of the Yb-catalyzed asymmetric Diels-Alder reaction of pyrone (I) and the electron-rich olefins (II) is remarkably enhanced by addition of oxyge
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