Dicyanobiphenyl polysioloxane stationary phases for capillary column gas chromatography
โ Scribed by A. Malik; S. L. Reese; S. Morgan; J. S. Bradshaw; M. L. Lee
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 491 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0009-5893
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๐ SIMILAR VOLUMES
Methyl-2-phenylethylpolysiloxane polymers have been synthesized for comparison with methylphenylpolysiloxane stationary phases for gas chromatography. The 50% 2-phenylethyl polysiloxane was found to be autocrosslinkable at 26OOC without addition of free radical initiator. Although the selectivity of
Nitrophenyl-, nitrophenylethyl-, dinitrophenylethyl-, and methoxynitrophenylethyl-substituted polysiloxanes (2S-S0% substitution) have been synthesized and evaluated as stationary phases in capillary column gas chromatography. Phases with 25% substitution and with ethylene spacers between the phenyl
## Abstract A new polar polysiloxane stationary phase for capillary column gas chromatography containing 4โ(methylsulfonyl)phenyl substitution was synthesized and compared to a cyanophenylpolysiloxane, OVโ225. The sulfonylphenylpolysiloxane phase was useful and stable over a wide temperature range