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Dichlorosilylene: rate constant for reaction with oxygen

✍ Scribed by V. Sandhu; A. Jodhan; I. Safarik; O.P. Strausz; T.N. Bell

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 228 KB
Volume: 135
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85152-7

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✦ Synopsis

Using the recently detected intense UV absorption spectrum of SiCl,(% 'A,) the absolute rate constant has been measured for its reaction with oxygen. The value of the bimolecular rate constant, k(SiCl,+O,), is equal to (3.4k0.7) x lo9 M-' s-' at 25°C.

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