Dichloro(N,N-dimethylethylenediamine)cadmium(II): a novel two-dimensional chloro-bridged coordination polymer
✍ Scribed by Bian, He-Dong ;Gu, Wen ;Yan, Shi-Ping ;Liao, Dai-Zheng ;Jiang, Zong-Hui
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 211 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Polymeric dichloro(N,N-dimethylethylenediamine)cadmium-(II), [CdCl 2 (C 4 H 12 N 2 )] n , has been synthesized and characterized by single-crystal X-ray diffraction. The two-dimensional polymeric sheet structure involves 12-membered zigzag rings formed by chloro bridges.
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The title compound, [CuCl 2 (C 11 H 24 N 2 )], crystallizes as fourcoordinate monomers with distorted square-planar geometry. The complex is chiral and forms racemic crystals. Molecules which have an S-con®guration at nitrogen have a !conformation of the ®ve-membered chelate ring, and those with R-c
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## Abstract A novel 3D polymeric Pb^II^ complex involving three different hemidirected Pb^II^ coordination spheres, [Pb~3~(phen)~3~(H~2~O)~2~(sip)~2~]~__n__~⋅3 H~2~O (phen=1,10‐phenanthroline and sip=5‐sulfoisophthalate=5‐sulfobenzene‐1,3‐dicarboxylate), was synthesized and characterized by element