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A Novel Three-Dimensional Coordination Polymer Involving PbPb Interactions and Three Different Hemidirected Lead(II) Coordination Spheres: X-Ray Crystal Structure of Tris(1,10-phenanthroline-κN1,κN10)bis[{μ3-[5-(sulfo-κO)benzene-1,3-dicarboxylate(3−)-κO1,κO1′ : κO2,κO2′ : κO2]}trilead (PbPb) Trihydrate ([Pb3(phen)3(H2O)2(sip)2]n⋅3 H2O)

✍ Scribed by Hong-Ping Xiao; Ali Morsali

Publisher: John Wiley and Sons
Year: 2005
Tongue: German
Weight: 190 KB
Volume: 88
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.200590192

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✦ Synopsis

Abstract

A novel 3D polymeric Pb^II^ complex involving three different hemidirected Pb^II^ coordination spheres, [Pb~3~(phen)~3~(H~2~O)~2~(sip)~2~]~n~⋅3 H~2~O (phen=1,10‐phenanthroline and sip=5‐sulfoisophthalate=5‐sulfobenzene‐1,3‐dicarboxylate), was synthesized and characterized by elemental analysis and IR spectroscopy. Its single‐crystal X‐ray structure shows three types of Pb^2+^ ions with coordination number six for Pb(1) and seven for Pb(2) and Pb(3). Two of the lead atoms, Pb(1) and Pb(3), are involved in PbPb interactions.

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