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Dichloro­(ethanol-κO){(E)-1-[1-(2-pyrid­yl)ethyl­idene]thio­semicarbazonato-κ3N,N′,S}indium(III)

✍ Scribed by Fan, Ying-Ju ;Wang, Le ;Ma, Jian-Ping ;Sun, Zhong-Xi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
129 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Reaction of indium(III) chloride with (E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazide afforded the title complex, [In(C~8~H~9~N~4~S)Cl~2~(C~2~H~5~OH)]. The ligand is in the enol form coordinating to the In^III^ atom through one S atom and two N atoms. The In^III^ atom is further coordinated by two Cl atoms and an ethanol molecule to complete a distorted octahedral coordination geometry.

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