The title complex, (C 6 H 18 N 2 )[V 2 Cl 5 (C 6 H 16 N 2 ) 2 ](C 24 H 20 B).-C 4 H 8 O, was prepared by the reaction of [V 2 Cl 3 (THF) 6 ](BPh 4 ) with [FeCl 2 (tmeda) 2 ] in the presence of one equivalent of tmeda (tmeda = N,N,N H ,N H -tetramethylethylenediamine) in methanol. The crystal structu
Dichlorobis(tetrahydrofuran)(N,N′-di-tert-butylethane-1,2-diamine)vanadium(II)
✍ Scribed by Niedwieski, Antonio Carlos ;Leigh, G. Jeffery ;Hasegawa, Tai ;Nunes, Fábio Souza
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 292 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.007 A Ê R factor = 0.026 wR factor = 0.061 Data-to-parameter ratio = 21.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.042 wR factor = 0.132 Data-to-parameter ratio = 10.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.