Dichloro[2-chloro-6-(mercaptopyridin-2-yl)pyridine]copper(II)
✍ Scribed by Blake, Alexander J. ;George, Michael W. ;Hubberstey, Peter ;Garcia, Roberto Lopez ;Wilson, Claire
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 280 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [CuCl 2 (C 6 H 5 Cl 2 N) 2 ], each Cu atom has a distorted tetrahedral coordination involving two Cl À anions and two 2-chloro-5-(chloromethyl)pyridine ligands. The molecular structure and packing are stabilized by intra-and intermolecular C-HÁ Á ÁCl hydrogen-bonding interacti
In the crystal structure of the title compound, C 6 H 4 Br 2 ClN, all atoms but Br are located on a crystallographic mirror plane. The crystal packing is stabilized by offsetstacking.
The title compound, [Cu 2 Cl 4 (C 10 H 8 N 2 ) 2 ], represents the first example of a simple dimeric coordination complex of Cu II and 2,2 0 -bipyridine (bpy). The metal is in a five-coordinate distorted square-pyramidal environment, bonded to a 2,2 0bipyridine molecule, two bridging chlorides and o
The title compound, [CuCl 2 (C 10 H 8 N 2 )], has twofold symmetry and the coordination geometry around the Cu II atom is distorted square-planar. There are weak intermolecular CuÁ Á ÁCl interactions, forming a chain structure in the crystal.