Dichloridobis(2-methyl-1,3-benzothiazole-κN)zinc(II)
✍ Scribed by Roh, Soo-Gyun ;Jeong, Jong Hwa
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 920 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [WCl~2~(C~12~H~8~N~2~)~2~], the W atom has a distorted six-coordinate octahedral geometry. There are some π–π stacking interactions in the structure, which are responsible for the supramolecular assembly.
Single-crystal X-ray study T = 102 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.073 wR factor = 0.150 Data-to-parameter ratio = 17.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title Zn II complex, [ZnCl 2 (C 6 H 10 N 2 O) 2 ], the Zn atom is coordinated by two Cl atoms and two imidazole N atoms in a distorted tetrahedral geometry. Weak intermolecular C-HÁ Á ÁO hydrogen bonding occurs between the methyl and methoxy groups.