metal-organic compounds m2540 Verguet et al. [Zr(Cl) 2 (C 21 H 25 N 2 )(C 9 H 7 )]Á0.5C 7 H 8
Dichlorido-[N,N′-bis(2,6-dimethylphenyl)pentane-2,4-diiminato](cyclopentadienyl)zirconium(IV)
✍ Scribed by Verguet, Emilie ;Oguadinma, Paul O. ;Schaper, Frank
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 814 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The nacnac (pentane-2,4-diiminato) ligand in the title compound, [Zr(C~21~H~25~N~2~)Cl~3~(C~4~H~8~O)], displays a κ^2^-coordination to the Zr center. Three chlorido ligands and a coordinated tetrahydrofuran (THF) molecule complete the octahedral environment of the metal. Despite the __C__ ~2~ symmet
The title complex, [Yb(C 9 H 12 )(C 26 H 42 N 2 )Cl] or {(2,6-Pr i 2 C 6 H 3 )NC(CH 3 )} 2 CH]( t BuC 5 H 4 )YbCl, exists as a monomeric molecule; the six-membered chelate ring adopts a boat conformation. The Yb atom is six-coordinate and the shape of the molecule approximates to a three-legged pian
The title compound, [TiCl~2~(C~31~H~28~O~4~)(C~16~H~16~N~2~)], is a titanium(IV) complex of the bidentate 2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolate (TADDOLate) ligand containing also two chloride ions and a bidentate neutral __N__,__N__′-dibenzylideneethane-1,2-diamine ligan