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Dichlorido-[N,N′-bis(2,6-dimethylphenyl)pentane-2,4-diiminato](indenyl)zirconium(IV) toluene hemisolvate

✍ Scribed by Verguet, Emilie ;Fortuné, Rose-Verla ;Oguadinma, Paul O. ;Schaper, Frank


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
965 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


metal-organic compounds m2540 Verguet et al. [Zr(Cl) 2 (C 21 H 25 N 2 )(C 9 H 7 )]Á0.5C 7 H 8


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[N,N′-Bis(2,6-dimethylphenyl)pentane-2,4
✍ Fortuné, Rose-Verla ;Verguet, Emilie ;Oguadinma, Paul O. ;Schaper, Frank 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 455 KB

The nacnac (pentane-2,4-diiminato) ligand in the title compound, [Zr(C~21~H~25~N~2~)Cl~3~(C~4~H~8~O)], displays a κ^2^-coordination to the Zr center. Three chlorido ligands and a coordinated tetrahydrofuran (THF) molecule complete the octahedral environment of the metal. Despite the __C__ ~2~ symmet