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Diastereoselective Intramolecular C−H bond Activation by Optically Active Tris(pyrazolyl)hydroborate Complexes of Rhodium

✍ Scribed by Keyes, Michael C.; Young, Victor G.; Tolman, William B.

Book ID
120430787
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
458 KB
Volume
15
Category
Article
ISSN
0276-7333

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✍ Wolfgang Kläui; Daniel Schramm; Wilfried Peters 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB

Irradiation of [(Tpms)Rh(CO)(PMe 3 )] (1) in benzene or [D 6 ]benzene affords the rhodium(III) compounds [(Tpms)-Rh(H)(C 6 H 5 )(PMe 3 )] (2) and [(Tpms)Rh(D)(C 6 D 5 )(PMe 3 )] (2d 6 ) respectively. The k H /k D ratio for the formation of 2 and 2d 6 was found to be 1.1. The complexes 2 and 2-d 6 ar