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Synthesis of Cycloalkanones from Dienes and Allylamines Through C—H and C—C Bond Activation Catalyzed by a Rhodium(I) Complex.

✍ Scribed by Dae-Yon Lee; In-Jung Kim; Chul-Ho Jun

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis of Cycloalkanones from Dienes
Synthesis of Cycloalkanones from Dienes and Allylamines through CH and CC Bond Activation Catalyzed by a Rhodium(I) Complex
✍ Dae-Yon Lee; In-Jung Kim; Chul-Ho Jun 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 2 views

Among numerous examples of transition-metal-mediated cyclization to obtain medium-sized ring compounds, [1] intramolecular hydroacylation provides the most promising way to prepare cyclopentanones from 4-pentenal through the CÀHbond activation of an aldehyde. [2, 3] However, its application has been