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Diastereoselective Epoxidation of N-Enoylsultams with Different Chiral Sultams as Auxiliaries

✍ Scribed by Shu-Jia Zhang; Yong-Kang Chen; Hui-Ming Li; Wei-Yang Huang; Viktor Rogatchov; Peter Metz


Book ID
102098124
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
132 KB
Volume
24
Category
Article
ISSN
0256-7660

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## Abstract A crude hydrate 6 and a crystalline hemiacetal 7 of glyoxylamide 4 were prepared from crotonamide 5 (__Scheme 2__). Particularly hemiacetal 7, but also 6 and the β€˜dimer’ 8 (obtained from 7) may serve as homochiral auxiliaries. The structure of 8 was determined by X‐ray analysis. By aren