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Chiral Auxiliary Controlled Diastereoselectivity in the Epoxidation of Enecarbamates with DMD and mCPBA.

✍ Scribed by Waldemar Adam; Sara G. Bosio; Barbara T. Wolff


Book ID
101949313
Publisher
John Wiley and Sons
Year
2003
Weight
153 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract High diastereoselectivity, but of the opposite sense, is observed in the epoxidation (DMD or __m__CPBA) of Ξ±,β‐unsaturated imides equipped with pyrrolidinone‐type chiral auxiliaries that bear either a hydroxymethyl or trityloxymethyl side chain. This unprecedented reversed π‐facial diff