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Diastereoselective allylboration of carbonyl derivatives of [2.2]paracyclophane

โœ Scribed by N. V. Voronstsova; V. I. Rozenberg; O. L. Tok; Yu. N. Bubnov


Book ID
105595741
Publisher
Springer
Year
1997
Tongue
English
Weight
134 KB
Volume
46
Category
Article
ISSN
1573-9171

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Diastereoselective Hartwigโ€“Buchwald Reac
โœ Michael Kreis; Christian J. Friedmann; Stefan Brรคse ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 169 KB ๐Ÿ‘ 1 views

## Abstract A Hartwigโ€“Buchwald addition of a variety of chiral amines to __rac__โ€4โ€bromoโ€[2.2]paracyclophane and __rac__โ€trifluoromethanesulfonic acid (4โ€[2.2]paracyclophane) ester was performed with high diastereoselectivities. Kinetic racemic resolution of the starting materials was achieved, pro