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ChemInform Abstract: Diastereoselective Allylboration of Carbonyl Derivatives of [2.2]Paracyclophane.

✍ Scribed by N. V. VORONTSOVA; V. I. ROZENBERG; O. L. TOK; YU. N. BUBNOV


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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Diastereoselective Hartwig–Buchwald Reac
✍ Michael Kreis; Christian J. Friedmann; Stefan Bräse 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 169 KB

## Abstract A Hartwig–Buchwald addition of a variety of chiral amines to __rac__‐4‐bromo‐[2.2]paracyclophane and __rac__‐trifluoromethanesulfonic acid (4‐[2.2]paracyclophane) ester was performed with high diastereoselectivities. Kinetic racemic resolution of the starting materials was achieved, pro