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Diastereoselective Addition of Grignard Reagents to Chiral α-Ketoimides Derived from Oppolzer′s Sultam.

✍ Scribed by K. Raszplewicz; L. Sikorska; K. Kiegiel; T. Balakier; J. Jurczak


Publisher
John Wiley and Sons
Year
2006
Weight
25 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Diastereoselective
✍ Katarzyna Kiegiel; Janusz Jurczak 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Diastereoselective Addition of Allylic Reagents to Chiral α-Ketoimides Derived from Oppolzer's Sultam. -Additions of allylic reagents (II), (V), and (VI) to the chiral sultam derivatives (I) is described. High diastereoselection in these reactions is observed and in the case of the allyl-Tms (VI)/T