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Diastereoselective 1,3-dipolar cycloadditions of both electronically modified phenyl-nitrile oxides and stilbenes

✍ Scribed by Romanski, Jan; Nowak, Piotr; Maksymiuk, Anna; Chapuis, Christian; Jurczak, Janusz

Book ID
121374874
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
887 KB
Volume
3
Category
Article
ISSN
2046-2069

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The 1,3-Dipolar Cycloadditions of Nitril
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## Abstract The readily available alkyl dicyanoacetates 1 reacted with the 1,3‐dipolar reagents arenecarbonitrile oxides 2β€² and arenecarbonitrile imines 5β€² to afford 1,2,4‐oxadiazol and 1,2,4‐triazol derivatives. The arenecarbonitrile oxides 2β€² with electron‐donating groups on the arene ring gave p