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Transition Structures of Diastereoselective 1,3-Dipolar Cycloadditions of Nitrile Oxides to Chiral Homoallylic Alcohols

✍ Scribed by Luft, Jennifer A. R.; Meleson, Kieche; Houk, K. N.


Book ID
126140395
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
173 KB
Volume
9
Category
Article
ISSN
1523-7060

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The 1,3-Dipolar Cycloadditions of Nitril
✍ Richard Neidlein; Zhihua Sui πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 German βš– 561 KB

## Abstract The readily available alkyl dicyanoacetates 1 reacted with the 1,3‐dipolar reagents arenecarbonitrile oxides 2β€² and arenecarbonitrile imines 5β€² to afford 1,2,4‐oxadiazol and 1,2,4‐triazol derivatives. The arenecarbonitrile oxides 2β€² with electron‐donating groups on the arene ring gave p