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Intermolecular 1,3-Dipolar Cycloadditions of Preformed Nitrile Oxides with Phenyl Vinyl Sulphone1

โœ Scribed by Lokanatha Rai, K. M.; Hassner, A.


Book ID
115477470
Publisher
Taylor and Francis Group
Year
1997
Tongue
English
Weight
288 KB
Volume
27
Category
Article
ISSN
0039-7911

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1,3-Dipolar cycloadditions of prop-1-ene
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The scope and limitations of dipolar cycloaddition reactions between nitrile oxides/nitrones and prop-1-ene-1,3-sultone have been investigated. A remarkably high degree of regioselectivity and stereoselectivity was observed. The homochiral sultam 8e was synthesized in a four-step reaction sequence s