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Diastereomeric DNA-Binding Geometries of Intercalated Ruthenium(II) Trischelates Probed by Linear Dichroism: [Ru(phen) 2 DPPZ] 2+ and [Ru(phen) 2 BDPPZ] 2+

✍ Scribed by Lincoln, Per; Broo, Anders; Nordén, Bengt


Book ID
121461090
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
265 KB
Volume
118
Category
Article
ISSN
0002-7863

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Synthesis, DNA-Binding and Photocleavage
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## Abstract Two new complexes, [Ru(phen)~2~(ppd)]^2+^ (**1**) and [Ru(phen)(ppd)~2~]^2+^ (**2**) (ppd=pteridino[6,7‐__f__] [1,10]phenanthroline‐11,13(10__H__,12__H__)‐dione, phen=1,10‐phenanthroline) were synthesized and characterized by ES‐MS, ^1^H‐NMR spectroscopy, and elemental analysis. The int