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DNA Binding Geometries of Ruthenium(II) Complexes with 1,10-Phenanthroline and 2,2‘-Bipyridine Ligands Studied with Linear Dichroism Spectroscopy. Borderline Cases of Intercalation

✍ Scribed by Lincoln, Per; Nordén, Bengt

Book ID: 111965807
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 505 KB
Volume: 102
Category: Article
ISSN: 0022-3654
DOI: 10.1021/jp9824914

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## Abstract New chiral complexes of the composition [MLL′], where HL=1,2‐bis(1__H__‐benzimidazol‐2‐yl)ethane‐1,2‐diol=H~2~bimedol, M=Co^II^, Ni^II^, Cu^II^, and L′=1,10‐phenanthroline (phen) or ethane‐1,2‐diamine (en), were synthesized and characterized. The ligand L exhibited a coordination mode i