Diastereocontrol in intermolecular diels-alder reactions of allenic lactones: Synthetic approach to the plaunols
β Scribed by Michael E. Jung; Craig N. Zimmerman; Gregory T. Lowen; Saeed I. Khan
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 108 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
A convergent route to the polyketide sesguiterpene skeleton of robustadial and euglobal is described. ## Simple nonactivated olefins have to our knowledge not yet been used systematically in intermolecular hetero Diels-Alder (HDA) reactions with 1-oxabutadienes as 4n component, although we have s
Abstraci: The endolexo selecttviry of Diels-Alder reactions tn water and methanol is studied with semiempirical methods using the SCRF approach and a combined quantum chemical (transition state) and molecular mechanics (solvent molecules) method lQCIMA4) to determine the effect of protic solvents on