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Application of intermolecular SCF-perturbation theory to the regioselectivity in the Diels-Alder reaction

โœ Scribed by Vinzenz Bachler; Franz Mark

Publisher
Springer
Year
1976
Tongue
English
Weight
784 KB
Volume
43
Category
Article
ISSN
1432-2234

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Ab5tract: 4-Ethyl-5-methyl-6-mthylthio-2(H)-pyranone (4) undergoes Dials-Alder reactions with ethyl hexynoate (5). 3-heptyn-2-one (6). ethyl ptopiolate (7). and3-butyn-2-one (8) to afford substituted banzenes with high ragioselectivity upon extrusion of CO2. 4-Ethyl-5.6-dimethyl-( 4-ethyl-3,6-dimeth