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Diaquabis[5-(pyrimidin-2-yl)tetrazolato]manganese(II)

✍ Scribed by Liu, Ju-Tao ;Fan, Sheng-Di

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 897 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807021885

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✦ Synopsis

The title complex, [Mn(C 5 H 3 N 6 ) 2 (H 2 O) 2 ], possesses a crystallographically imposed center of symmetry occupied by an Mn II ion, which is coordinated by four N atoms from two 5-(pyrimidin-2-yl)tetrazolate ligands [Mn-N = 2.2066 (13) and 2.2731 (15) A ˚] and two water molecules [Mn-O = 2.1868 (14) A ˚] in a distorted octahedral geometry. In the crystal structure, intermolecular O-HÁ Á ÁN hydrogen bonds link the complexes into two-dimensional sheets parallel to the bc plane.

Related literature

The synthesis of 2-(1H-tetrazol-5-yl)pyrimidine was described by Demko & Sharpless (2001); for the crystal structures of related complexes, see:

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